Publications (pdf)            back                Tim Hubin          tim.hubin@swosu.edu

“CXCR4 chemokine receptor antagonists: nickel(II) complexes of configurationally restricted macrocycles” Smith, R.; Huskens, D.; Daelemans, D.; Mewis, R. E.; Garcia, C. D.; Cain, A. N.; Carder Freeman, T. N.; Pannecouque, C.; De Clercq, E.; Schols, D.; Hubin, T. J.; Archibald, S. J. Dalton Trans., 2012, 41, 11369-11377.

“Preparations and applications of synthetic linked azamacrocycle ligands and complexes” Timmons, J. C.; Hubin, T. J. Coord. Chem. Rev. 2010, 254, 1661-1685.

“Improving target residence time for metallodrugs by optimised coordination chemistry: fixed geometry CXCR4 chemokine receptor antagonists with improved anti-HIV properties” Khan, A.; Nicholson, G.; Greenman, J.; Madden, L.; McRobbie, G.; Pannecouque, C.; De Clercq, E.; Silversides, J. D.; Ullom, R.; Maples, D. L.; Maples, R. D.; Hubin, T. J.; Archibald, S. J. J. Am. Chem. Soc. 2009, 131, 3416-3417.

“Synthesis and Characterization of the chromium(III) complexes of ethylene cross-bridged cyclam and cyclen ligands” Maples, D. L.; Maples, R. D.; Hoffert, W. A.; Parsell, T. H.; van Asselt, A.; Silversides, J. D.; Archibald, S. J.; Hubin, T. J. Inorg. Chim. Acta 2009, 362, 2084-2088.

“The design and synthesis of pyrazine amide ligands suitable for the ‘‘tiles’’ approach to molecular weaving with octahedral metal ions” Cockriel, D.; McClain, J. M.; Patel, K. C.; Ullom, R.; Hasley, T. R.; Archibald, S. J.; Hubin, T. J. Inorg. Chem. Commun. 2008, 11, 1-4.

“Configurationally-restricted bismacrocyclic CXCR4 receptor antagonists” Valks, G. C.; McRobbie, G.; Lewis, E. A.; Hubin, T. J.; Hunter, T. M.; Sadler, P. J.; Pannecouque, C.; De Clerq, E.; Archibald, S. J.; J. Med. Chem., 2006, 49, 6162-6165.

“Dichloro(4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane)-iron(III) hexafluorophosphate” McClain, J. M.; Maples, D. L.; Maples, R. D.; Matz, D. L.; Harris, S. M.; Nelson, A. D.; Silversides, J. D.; Archibald, A.S. A.; Hubin, T. J. Acta Cryst. C, 2006, C62, m553.

“Configurationally restricted bis-azamacrocycles: chemokine receptor antagonists” Khan A.; McRobbie G.; Madden L. A.; Empson C. J.; Bridgeman A. J.; Ullom R.; Hubin T. J.; Greenman J.; Archibald S. J. Immunology, 2005, 116, 75.

“Rigidity extremes in coordination chemistry: a fine energetic balance in the isolation of a trapped ligand inversion intermediate” May, C. M.; Archibald, S. J.; Bridgeman, A. J.; Empson, C. J.; Hubin, T. J. J. Chem. Soc., Chem. Commun., 2004, 1880.

“Synthesis and characterization of the cobalt(III) complexes of two pendant-arm cross-bridged cyclams” Lichty, J.; Allen, S. M.; Grillo, A. I.; Archibald, S. J.; Hubin, T. J. Inorg. Chim. Acta, 2004, 357, 615.

“Synthesis and coordination chemistry of topologically constrained azamacrocycles” Hubin, T. J. Coord. Chem. Rev., 2003, 241, 27.

“Synthesis, structure, and stability in acid of copper(II) and zinc(II) complexes of cross-bridged tetraazamacrocycles” Hubin, T. J.; Alcock, N. W.; Morton, M. D.; Busch, D. H. Inorg. Chim. Acta, 2003, 348, 33.

“Synthesis and X-ray crystal structures of iron(II) and manganese(II) complexes of unsubstituted and benzyl substituted cross-bridged tetraazamacrocycles” Hubin, T. J.; McCormick, J. M.; Collinson, S. R.; Alcock, N. W.; Clase, H. J.; Busch, D. H. Inorg. Chim. Acta, 2003, 346, 76. 

“Synthesis and X-ray crystal structure determination of the first copper(II) complexes of tetraazamacrocycle-glyoxal condensates” Hubin, T. J.; Alcock, N. W.; Busch, D. H. Inorg. Chem., 2002, 41, 7006.

“Synthesis, characterization, and X-ray crystal structures of cobalt(II) and cobalt(III) complexes of four topologically constrained tetraazamacrocycles” Hubin, T. J.; Alcock, N. W.; Clase, H. J.; Seib, L.; Busch, D. H. Inorg. Chim. Acta, 2002, 337, 91.

“Potentiometric titrations and nickel(II) complexes of four topologically constrained tetraazamacrocycles” Hubin, T. J.; Alcock, N. W.; Clase, H. J.; Busch, D. H. Supramol. Chem., 2001, 13, 261.

“Synthesis and characterization of the novel rigid ligand 5,8-dimethyl-1,5,8,12-tetraazabicyclo[10.3.2]heptadecane and its complexation chemistry with Fe(II) and Mn(II) ions” Collinson, S. R.; Hubin, T. J.; Alcock, N. W.; Busch, D. H. J. Coord. Chem., 2001, 52, 317.

trans-Dioxocyclam (1,4,8,11-tetraazacyclotetradecane-2,9-dione) dihydrate and its Ni(II) complex” Hubin, T. J.; Tyryshkin, N.; Alcock, N. W; Busch, D. H. Acta Cryst. C, 2001, 57, 359.

“Topologically constrained manganese(III) and iron(III) complexes of two cross-bridged tetraazamacrocycles” Hubin, T. J.; McCormick, J. M.; Alcock, N. W.; Busch, D. H. Inorg. Chem., 2001, 40, 435.

“Template routes to interlocked molecular structures and orderly molecular entanglements” Hubin, T. J.; Busch, D. H. Coord. Chem. Rev., 2000, 200, 5.

“New iron(II) and manganese(II) complexes of two ultra-rigid, cross-bridged tetraazamacrocycles for catalysis and biomimicry” Hubin, T. J.; McCormick, J. M.; Collinson, S. R.; Perkins, C. M.; Alcock, N. W.; Kahol, P. K.; Raghunathan, A.; Busch, D. H. J. Am. Chem. Soc., 2000, 122, 2512.

“Cu(I) and Cu(II) complexes of an ethylene cross-bridged cyclam” Hubin, T. J.; Alcock, N. W.; Busch, D. H., Acta Cryst. C, 2000, 56, 37.

“A cyclam-like macrocycle side-bridged by a propyl chain” Hubin, T. J.; Alcock, N. W.; Busch, D. H. Acta Cryst. C, 1999, 55, 2188.  

“An o-xylyl cross-bridged 5,12-dioxocyclam” Hubin, T. J.; Tyryshkyn, N.; Alcock, N. W.; Busch, D. H. Acta Cryst. C, 1999, 55, 1888.  

“Crystallographic characterization of stepwise changes in ligand conformations as their internal topology changes, and two novel cross-bridged tetraazamacrocycle copper(II) complexes” Hubin, T. J.; McCormick, J. M.; Alcock, N. W.; Clase, H. J.; Busch, D. H. Inorg. Chem., 1999, 38, 4435.

“A complex containing copper(I) linearly coordinated by two tetracyclic tetraamines” Hubin, T. J.; Alcock, N. W.; Clase, H. J.; Busch, D. H. Acta Cryst. C, 1999, 55, 1402.

“The square pyramidal Pd(II) complex of a cross-bridged tetraazamacrocycle” Hubin, T. J.; Alcock, N. W.; Busch, D. H. Acta Cryst. C, 1999, 55, 1404.

“Template control of supramolecular architecture” Hubin, T. J.; Kolchinski, A. G.; Vance, A. L.; Busch, D. H. in Advances in Supramolecular Chemistry; Gokel, G. W., Ed.; JAI Press Inc.: Stamford, CT, USA, 1999, Vol. 5, p. 237.

“Synthesis and X-ray crystal structure determination of the first transition metal complexes of the tetracycles formed by tetraazamacrocycle-glyoxal condensation: PdL*Cl2” Hubin, T. J.; McCormick, J. M.; Alcock, N. W.; Busch, D. H. Inorg. Chem., 1998, 37, 6549.

“Ultra rigid cross-bridged tetraazamacrocycles as ligands--the challenge and the solution” Hubin, T. J.; McCormick, J. M.; Collinson, S. R.; Alcock, N. W.; Busch, D. H. J. Chem. Soc., Chem. Commun., 1998, 1675.