ORG CHEM II STUDY GUIDE
SPRING 2002


Links to Study Guides for Chapters 17-27 and Chapter 29 in Organic Chemistry 4th Edition by John McMurry

Dr. William J. Kelly
CPP 201C
774-3202
E-Mail: kellyw@swosu.edu


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CHAPTER 16
ELECTROPHILIC AROMATIC SUBSTITUTION

READ

Chapter 16, all sections

VOCABULARY

electrophilic aromatic substitution, halogenation, nitration, sulfonation, Friedel-Crafts alkylation/acylation, ortho/para directors, meta directors, activting, deactivating, resonance effects, inductive effects, nucleophilic aromatic substitution, benzyne

STUDY QUESTIONS

ASSIGNED PROBLEMS

5, 6, 8 - 11, 13, 15, 18, 19, 21-24, 27, 29, 31-36, 40, 42-44, 47, 48, 50, 63 Top of page




CHAPTER 10
ALKYL HALIDES

READ

Chapter 10, ALL SECTIONS

VOCABULARY

STUDY QUESTIONS

ASSIGNED PROBLEMS

1, 3, 4, 7,13,15, 16, 18, 19, 20,28, 29, 30, 33, 34Top of page


CHAPTER 11
NUCLEOPHILIC SUBSTITUTION AND ELIMINATION

READ

Chapter 11, all sections

VOCABULARY

substitution, elimination, SN2 reaction, SN1 reaction, rate-limiting step, second order kinetics, first order kinetics, E2 reaction, anti-elimination, Zaitsev's Rule, E1 reaction

STUDY QUESTIONS

ASSIGNED PROBLEMS

1,2,3,4,6,9,10,15,16,20,21,23,25,28-31 Top of page


CHAPTER 17
ALCOHOLS AND THIOLS

READ

Chapter 17, Sec 1-10

VOCABULARY

Tosylate, Hydrogen Bonding, Diol, Oxidation, Reduction, Carboxylic Acid, Jones Reagent, PCC, Grignard Reagent

STUDY QUESTIONS

ASSIGNED PROBLEMS

1, 2, 4, 6-11, 13-15, 18, 19, 22-26,28,29-33,35,36,39,Top of page


CHAPTER 18
ETHERS, EPOXIDES and SULFIDES

READ

Chapter 18, Sec 1-9 and 11

VOCABULARY

Williamson Ether Synthesis, Epoxide, Peracid

STUDY QUESTIONS

ASSIGNED PROBLEMS

1, 4, 5, 7, 8, 10-14 17-22, 24, 26, 27, 45-47Top of page


CHAPTER 19
ALDEHYDES AND KETONES

READ

Chapter 19 all sections

VOCABULARY

Acetal, Ketal, Imine, Hydrazone, Oxime, Enamine, Hemiacetal, Betaine, Ylide

STUDY QUESTIONS

ASSIGNED PROBLEMS

1-7,11-18, 23, 25, 27-29,31, 32, 34, 36-38,40,43, 45Top of page


CHAPTER 20
CARBOXYLIC ACIDS

READ

Chapter 20, sec. 1-8

VOCABULARY

Acyl group, Carboxylation, Decarboxylation, Hunsdiecker reaction, Oxidative cleavage

STUDY QUESTIONS

ASSIGNED PROBLEMS

1,-4,6,9-11,12, 13, 16, 17,19-21,25, 28,30,32,38, 45Top of page


CHAPTER 21
CARBOXYLIC ACID DERIVATIVES

READ

Chapter 21, sec. 1-10

VOCABULARY

Acid halides, Acid anhydrides, Esters, Amides, Nucleophilic Acyl Substitution, Hydrolysis, Alcoholysis, Aminolysis, Nitriles

STUDY QUESTIONS

ASSIGNED PROBLEMS

31,32,34,35,36,37,38,39,40,41,43,47,48,49,51,52,53,54,57,58Top of page


CHAPTER 22
CARBONYL ALPHA-SUBSTITUTION REACTIONS

READ

Sections 22.1-22.8

CONCEPTS

ASSIGNED PROBLEMS

1, 5, 8-9, 13-15, 18-23,25,28,30-33,36,44,46 Top of page


CHAPTER 23
CARBONYL CONDENSATION REACTIONS

READ

Chapter 23, all sections

VOCABULARY

Carbonyl condensation reaction, Aldol reaction, Claisen reaction, Dieckmann cyclization, Stork enamine rection, Michael reaction, Robinson annulation reaction/P>

STUDY QUESTIONS

ASSIGNED PROBLEMS

27,29,30,31,32,33,35,37,39,41,42,26,47,50,51,53


CHAPTER 24
ALIPHATIC AMINES

READ

Chapter 24, Sec 1-10

VOCABULARY

Gabriel synthesis
Curtius synthesis
Hinsberg test
Hofmann rearrangement
Hofmann elimination
Resolution of Enantiomers

STUDY QUESTIONS

ASSIGNED PROBLEMS

1-4, 6-13, 15-16, 21-22, 24,26, 28, 31-33Top of page


CHAPTER 25
ARYLAMINES AND PHENOLS

READ

Chapter 25, sec 1-8

VOCABULARY

Arylamines, Arenediazonium salts, Sandmeyer reaction, Phenols, Quinones, Claisen rearrangement

STUDY QUESTIONS

ASSIGNED PROBLEMS

17, 18, 19, 20, 21, 22, 24, 26, 27, 28, 30, 31, 33, 34Top of page


CHAPTER 26
BIOMOLECULES: CARBOHYDRATES

READ

Chapter 26 sec 1-12

VOCABULARY

Carbohydrates, Aldoses, Ketoses, D/L sugars, Furanose, Pyranose, Anomer, Mutarotation, Fischer projection, Haworth projection, Alditol, Aldonic acid Aldaric acid, Glycoside Furanoside, Pyranoside Disaccharide, Polysaccharide, Kiliani-Fischer synthesis, Wohl degradation

STUDY QUESTIONS

ASSIGNED PROBLEMS

27,28,29,31,33,34,37,38,39,40,43,44Top of page



Return to CHEM 4113/4115 Syllabus
Return to CHEMISTRY HOME PAGE

Dr. William J. Kelly
CPP 201C
774-3202
E-Mail: kellyw@swosu.edu